There are two broad categories of biogas storage systems: Internal Biogas Storage Tanks are integrated into the anaerobic digester while External Biogas Holders are separated from the digester forming autonomous components of a biogas plant. The simplest and least expensive storage systems for on-site applications and intermediate storage of biogas are low-pressure systems. The energy, safety, and scrubbing requirements of medium- and high-pressure storage systems make them costly and high-maintenance options for non-commercial use. Such extra costs can be best justified for biomethane or bio-CNG, which has a higher heat content and is therefore a more valuable fuel than biogas.

Low-Pressure Storage of Biogas

Floating gas holders on the digester form a low-pressure storage option for biogas systems. These systems typically operate at pressures below 2 psi. Floating gas holders can be made of steel, fiberglass, or a flexible fabric. A separate tank may be used with a floating gas holder for the storage of the digestate and also storage of the raw biogas. A major advantage of a digester with an integral gas storage component is the reduced capital cost of the system.

The least expensive and most trouble-free gas holder is the flexible inflatable fabric top, as it does not react with the H₂S in the biogas and is integral to the digester. These types of covers are often used with plug-flow and complete-mix digesters. Flexible membrane materials commonly used for these gas holders include high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low density polyethylene (LLDPE), and chlorosulfonated polyethylene covered polyester. Thicknesses for cover materials typically vary from 0.5 to 2.5 millimeters.

Medium-Pressure Storage of Cleaned Biogas

Biogas can also be stored at medium pressure between 2 and 200 psi. To prevent corrosion of the tank components and to ensure safe operation, the biogas must first be cleaned by removing H₂S. Next, the cleaned biogas must be slightly compressed prior to storage in tanks.

High-Pressure Storage of Compressed Biomethane

The typical composition of raw biogas does not meet the minimum CNG fuel specifications. In particular, the CO₂ and sulfur content in raw biogas is too high for it to be used as vehicle fuel without additional processing. Biogas that has been upgraded to biomethane by removing the H₂S, moisture, and CO₂ can be used as a vehicular fuel. Biomethane is less corrosive than biogas, apart from being more valuable as a fuel. Since production of such fuel typically exceeds immediate on-site demand, the biomethane must be stored for future use, usually either as compressed biomethane (CBM) or liquefied biomethane (LBM).

Two of the main advantages of LBM are that it can be transported relatively easily and it can be dispensed to either LNG vehicles or CNG vehicles. Liquid biomethane is transported in the same manner as LNG, that is, via insulated tanker trucks designed for transportation of cryogenic liquids.

Biomethane can be stored as CBM to save space. The gas is stored in steel cylinders such as those typically used for storage of other commercial gases. Storage facilities must be adequately fitted with safety devices such as rupture disks and pressure relief valves. The cost of compressing gas to high pressures between 2,000 and 5,000 psi is much greater than the cost of compressing gas for medium-pressure storage. Because of these high costs, the biogas is typically upgraded to biomethane prior to compression.

The term ‘crop residues’ covers the whole range of biomass produced as by-products from growing and processing crops. Crop residues encompasses all agricultural wastes such as bagasse, straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. Wheat and barley are the major staple crops grown in the Middle East region. In addition, significant quantities of rice, maize, lentils, chickpeas, vegetables and fruits are produced throughout the region, mainly in Egypt, Syria, Saudi Arabia and Jordan.

In Egypt, crop residues are considered to be the most important and traditional source of domestic fuel in rural areas. These crop residues are by-products of common crops such as cotton, wheat, maize and rice. The total amount of residues reaches about 16 million tons of dry matter per year. Cotton residues represent about 9% of the total amount of residues. These are materials comprising mainly cotton stalks, which present a disposal problem. The area of cotton crop cultivation accounts for about 5% of the cultivated area in Egypt

Large quantities of crop residues are produced annually in the region, and are vastly underutilised. Current farming practice is usually to plough these residues back into the soil, or they are burnt, left to decompose, or grazed by cattle. These residues could be processed into liquid fuels or thermochemical processed to produce electricity and heat in rural areas. Energy crops, such as Jatropha, can be successfully grown in arid regions for biodiesel production. Infact, Jatropha is already grown at limited scale in some Middle East countries and tremendous potential exists for its commercial exploitation.

Palm Kernel Shells (PKS)

Palm kernel shells (or PKS) are the shell fractions left after the nut has been removed after crushing in the Palm Oil mill. Kernel shells are a fibrous material and can be easily handled in bulk directly from the product line to the end use. Large and small shell fractions are mixed with dust-like fractions and small fibres.

Moisture content in kernel shells is low compared to other biomass residues with different sources suggesting values between 11% and 13%. Palm kernel shells contain residues of Palm Oil, which accounts for its slightly higher heating value than average lignocelluloses Biomass. Compared to other residues from the industry, it is a good quality Biomass fuel with uniform size distribution, easy handling, easy crushing, and limited biological activity due to low moisture content.

Press fibre and shell generated by the Palm Oil mills are traditionally used as solid fuels for steam boilers. The steam generated is used to run turbines for electricity production. These two solid fuels alone are able to generate more than enough energy to meet the energy demands of a Palm Oil mill.

Empty Fruit Bunches (EFBs)

In a typical Palm Oil mill, empty fruit bunches are abundantly available as fibrous material of purely biological origin. EFB contains neither chemical nor mineral additives, and depending on proper handling operations at the mill, it is free from foreign elements such as gravel, nails, wood residues, waste etc. However, it is saturated with water due to the biological growth combined with the steam sterilization at the mill. Since the moisture content in EFB is around 67%, pre-processing is necessary before EFB can be considered as a good fuel.

In contrast to shells and fibers, empty fruit bunches are usually burnt causing air pollution or returned to the plantations as mulch. Empty fruit bunches can be conveniently collected and are available for exploitation in all Palm Oil mills. Since shells and fibres are easy-to-handle, high quality fuels compared to EFB, it will be advantageous to utilize EFB for on-site energy demand while making shells and fibres available for off-site utilization which may bring more revenues as compared to burning on-site.

Palm Oil Mill Effluent (POME)

Palm Oil processing also gives rise to highly polluting waste-water, known as Palm Oil Mill Effluent, which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME could be used for biogas production through anaerobic digestion. At many Palm-oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off.

In a conventional Palm Oil mill, 600-700 kg of POME is generated for every ton of processed FFB. Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Liquid effluents from palm oil mills can be anaerobically converted into biogas which in turn can be used to generate power through gas turbines or gas-fired engines.

Conclusions

Most of the Biomass residues from Palm Oil Mills are either burnt in the open or disposed off in waste ponds. The Palm Oil industry, therefore, contributes significantly to global climate change by emitting carbon dioxide and methane. Like sugar mills, Palm Oil mills have traditionally been designed to cover their own energy needs (process heat and electricity) by utilizing low pressure boilers and back pressure turbo-generators. Efficient energy conversion technologies that can utilize all Palm Oil residues, including EFBs, are currently available.

In the Palm Oil value chain there is an overall surplus of by-products and their utilization rate is negligible, especially in the case of POME and EFBs. For other mill by-products the efficiency of the application can be increased. Presently, shells and fibers are used for in-house energy generation in mills but empty fruit bunches is either used for mulching or dumped recklessly. Palm Oil industry has the potential of generating large amounts of electricity for captive consumption as well as export of surplus power to the public grid.

Electricity generated from biomass is more costly to produce than fossil fuel and hydroelectric power for two reasons. First, biomass fuels are expensive. The cost of producing biomass fuel is dependent on the type of biomass, the amount of processing necessary to convert it to a fuel, distance to the energy plant, and supply and demand for fuels in the market place. Biomass fuel is low-density and non-homogeneous and has a small unit size.

Consequently, biomass fuel is costly to collect, process, and transport to facilities.  Second, biomass-to-energy facilities are much smaller than conventional fossil fuel power plants and therefore cannot produce electricity as cost-effectively as the fossil plants.

Agro biomass is costly to collect, process, and transport to facilities.

The biomass-to-energy facilities are smaller because of the limited amount of fuel that can be stored at a single facility. With higher fuel costs and lower economic efficiencies, solid-fuel energy is not economically competitive in a deregulated energy market that gives zero value or compensation for the non-electric benefits generated by the biomass-to-energy industry.

Biomass availability for fuel usage is estimated as the total amount of plant residue remaining after harvest, minus the amount of plant material that must be left on the field for maintaining sufficient levels of organic matter in the soil and for preventing soil erosion. While there are no generally agreed-upon standards for maximum removal rates, a portion of the biomass material may be removed without severely reducing soil productivity.

Technically, biomass removal rates of up to 60 to 70 percent are achievable, but in practice, current residue collection techniques generally result in relatively low recovery rates in developing countries. The low biomass recovery rate is the result of a combination of factors, including collection equipment limitations, economics, and conservation requirements. Modern agricultural equipment can allow for the joint collection of grain and residues, increased collection rates to up to 60 percent, and may help reduce concerns about soil compaction.

Solid waste generation in the three largest cities – Riyadh, Jeddah and Dammam – exceeds 6 million tons per annum which gives an indication of the magnitude of the problem faced by civic bodies.  More than 75 percent of the population is concentrated in urban areas which make it necessary for the government to initiate measures to improve recycling and waste management scenario in the country.

In Saudi Arabia, municipal solid waste is collected from individual or community bins and disposed of in landfills or dumpsites. Saudi waste management system is characterized by lack of waste disposal and tipping fees. Recycling, reuse and energy recovery is still at an early stage, although they are getting increased attention. Waste sorting and recycling are driven by an active informal sector. Recycling rate ranges from 10-15%, mainly due to the presence of the informal sector which extracts paper, metals and plastics from municipal waste.

Recycling activities are mostly manual and labor intensive. Composting is also gaining increased interest in Saudi Arabia due to the high organic content of MSW (around 40%).  Efforts are also underway to deploy waste-to-energy technologies in the Kingdom. All activities related to waste management are coordinated and financed by the government.

The Saudi government is aware of the critical demand for waste management solutions, and is investing heavily in solving this problem. The 2011 national budget allocated SR 29 billion for the municipal services sector, which includes water drainage and waste disposal. The Saudi government is making concerted efforts to improve recycling and waste disposal activities.

Moisture limits must be observed to avoid spontaneous combustion and the emission of regulated compounds. Cost of storage is important to the overall feasibility of the biomass enterprise. In some cases, the storage can be on the same site as the source of the feedstock. In others, necessary volumes can only be achieved by combining the feedstock from a number of relatively close sources. Typically, delivery within about 50 miles is economic, but longer‐range transport is sometimes acceptable, especially when disposal fees can be reduced.

Agricultural residues such as wheat straw, rice husk, rice straw and corn stover are usually spread or windrowed behind the grain harvesters for later baling. Typically these residues are left in the field to air dry to moisture levels below about 14% preferred for bales in stacks or large piles of loose material. After collection, biomass may be stored in the open or protected from the elements by tarps or various structures. Pelletizing may be employed to increase bulk density and reduce storage and transport volume and cost.

Biomass Storage Options

• Feedstock is hauled directly to the plant with no storage at the production site.
• Feedstock is stored at the production site and then transported to the plant as needed.
• Feedstock is stored at a collective storage facility and then transported to the plant from the intermediate storage location.

Biomass Storage Systems

The type of storage system used at the production site, intermediate site, or plant can greatly affect the cost and the quality of the fuel. The most expensive storage systems, no doubt, are the most efficient in terms of maintaining the high fuel quality. Typical storage systems, ranked from highest cost to lowest cost, include:

• Enclosed structure with crushed rock floor
• Open structure with crushed rock floor
• Reusable tarp on crushed rock
• Outside unprotected on crushed rock
• Outside unprotected on ground

The storage of biomass is often necessary due to its seasonal production versus the need to produce energy all year round. Therefore to provide a constant and regular supply of fuel for the plant requires either storage or multi-feedstocks to be used, both of which tend to add cost to the system.

Reducing the cost of handling and stable storage of biomass feedstocks are both critical to developing a sustainable infrastructure capable of supplying large quantities of biomass to biomass processing plants.

Several organic wastes from plants and animals have been exploited for biogas production as reported in the literature. Plant materials include agricultural crops such as sugar cane, cassava, corn etc, agricultural residues like rice straw, cassava rhizome, corn cobs etc, wood and wood residues (saw dust, pulp wastes, and paper mill.

Others include molasses and bagasse from sugar refineries, waste streams such as rice husk from rice mills and residues from palm oil extraction and municipal solid wastes, etc. However, plant materials such as crop residues are more difficult to digest than animal wastes (manures) because of difficulty in achieving hydrolysis of cellulosic and lignocellulosic constituents.

Crop residues can be digested either alone or in co-digestion with other materials, employing either wet or dry processes. In the agricultural sector one possible solution to processing crop biomass is co-digestion together with animal manures, the largest agricultural waste stream. In addition to the production of renewable energy, controlled anaerobic digestion of animal manures reduces emissions of greenhouse gases, nitrogen and odour from manure management, and intensifies the recycling of nutrients within agriculture.

In co-digestion of plant material and manures, manures provide buffering capacity and a wide range of nutrients, while the addition of plant material with high carbon content balances the carbon to nitrogen (C/N) ratio of the feedstock, thereby decreasing the risk of ammonia inhibition.

The gas production per digester volume can be increased by operating the digesters at a higher solids concentration. Batch high solids reactors, characterized by lower investment costs than those of continuously fed processes, but with comparable operational costs, are currently applied in the agricultural sector to a limited extent.

Codigestion offers good opportunity to farmers to treat their own waste together with other organic substrates. As a result, farmers can treat their own residues properly and also generate additional revenues by treating and managing organic waste from other sources and by selling and/or using the products viz heat, electrical power and stabilised biofertiliser.

Sugar factories in Mauritius produce about 600,000 tons of sugar from around 5.8 million tons of sugarcane which is cultivated on an agricultural area of about 72,000 hectares. Of the total sugarcane production, around 35 percent is contributed by nearly 30,000 small growers. There are more than 11 sugar factories presently operating in Mauritius having crushing capacities ranging from 75 to 310 tons cane per hour.

During the sugar extraction process, about 1.8 million tons of Bagasse is produced as a by-product, or about one third of the sugarcane weight. Traditionally, 50 percent of the dry matter is harvested as cane stalk to recover the sugar with the fibrous fraction, i.e. Bagasse being burned to power the process. Most factories in Mauritius have been upgraded and now export electricity to the grid during crop season, with some using coal to extend production during the intercrop season.

Surplus electricity is generated in almost all the sugar mills. The total installed capacity within the sugar industry is 243 MW out of which 140 MW is from firm power producers. Around 1.6 – 1.8 million tons of bagasse (wet basis) is generated on an annually renewable basis and an average of around 60 kWh per ton sugarcane is generated for the grid throughout the island. The surplus exportable electricity in Mauritian power plants has been based on a fibre content ranging from 13- 16% of sugarcane, 48% moisture content in Bagasse, process steam consumption of 350–450 kg steam per ton sugarcane and a power consumption of 27-32 kWh per ton sugarcane.

In Mauritius, the sugarcane industry is gradually increasing its competitiveness in electricity generation. It has revamped its boiler houses by installing high pressure boilers and condensing extraction steam turbine. All the power plants are privately owned, and the programme has been a landmark to show how all the stakeholders (government, corporate and small planters) can co-operate. The approach is being recommended to other sugarcane producing countries worldwide to harness the untapped renewable energy potential of biomass wastes from the sugar industry.

The composition of Bagasse depends on the variety and maturity of Sugarcane as well as harvesting methods applied and efficiency of the Sugar processing. Bagasse is usually combusted in furnaces to produce steam for power generation. Bagasse is also emerging as an attractive feedstock for bioethanol production. It is also utilized as the raw material for production of paper and as feedstock for cattle. The value of Bagasse as a fuel depends largely on its calorific value, which in turn is affected by its composition, especially with respect to its water content and to the calorific value of the Sugarcane crop, which depends mainly on its sucrose content.

Moisture contents is the main determinant of calorific value i.e. the lower the moisture content, the higher the calorific value. A good milling process will result in low moisture of 45% whereas 52% moisture would indicate poor milling efficiency. Most mills produce Bagasse of 48% moisture content, and most boilers are designed to burn Bagasse at around 50% moisture. Bagasse also contains approximately equal proportion of fibre (cellulose), the components of which are carbon, hydrogen and oxygen, some sucrose (1-2 %), and ash originating from extraneous matter. Extraneous matter content is higher with mechanical harvesting and subsequently results in lower calorific value.

For every 100 tons of Sugarcane crushed, a Sugar factory produces nearly 30 tons of wet Bagasse. Bagasse is often used as a primary fuel source for Sugar mills; when burned in quantity, it produces sufficient heat and electrical energy to supply all the needs of a typical Sugar mill, with energy to spare. The resulting CO₂ emissions are equal to the amount of CO₂ that the Sugarcane plant absorbed from the atmosphere during its growing phase, which makes the process of cogeneration greenhouse gas-neutral.

35MW Bagasse and Coal CHP Plant in Mauritius

Cogeneration of Bagasse is one of the most attractive and successful energy projects that have already been demonstrated in many Sugarcane producing countries such as Mauritius, Reunion Island, India and Brazil. Combined heat and power from Sugarcane in the form of power generation offers renewable energy options that promote sustainable development, take advantage of domestic resources, increase profitability and competitiveness in the industry, and cost-effectively address climate mitigation and other environmental goals.

Anaerobic digestion is a unique treatment solution for animal wastes as it can  deliver  positive  benefits  related  to  multiple  issues,  including  renewable  energy,  water pollution, and air emissions. Anaerobic digestion of animal manure is gaining popularity as a means to protect the environment and to recycle materials efficiently into the farming systems. Waste-to-Energy (WTE) plants, based on anaerobic digestion of cow manure, are highly efficient in harnessing the untapped renewable energy potential of organic waste by converting the biodegradable fraction of the waste into high calorific gases.

The establishment of anaerobic digestion systems for livestock manure stabilization and energy production has accelerated substantially in the past several years. There are thousands of digesters operating at commercial livestock facilities in Europe, United States,  Asia and elsewhere. which are generating clean energy and fuel. Many of the projects that generate electricity also capture waste heat for various in-house requirements.

Important Factors

The main factors that influence biogas production from livestock manure are pH and temperature of the feedstock. It is well established that a biogas plant works optimally at neutral pH level and mesophilic temperature of around 35^o C. Carbon-nitrogen ratio of the feed material is also an important factor and should be in the range of 20:1 to 30:1. Animal manure has a carbon – nitrogen ratio of 25:1 and is considered ideal for maximum gas production. Solid concentration in the feed material is also crucial to ensure sufficient gas production, as well as easy mixing and handling. Hydraulic retention time (HRT) is the most important factor in determining the volume of the digester which in turn determines the cost of the plant; the larger the retention period, higher the construction cost.

Process Description

The fresh animal manure is stored in a collection tank before its processing to the homogenization tank which is equipped with a mixer to facilitate homogenization of the waste stream. The uniformly mixed waste is passed through a macerator to obtain uniform particle size of 5-10 mm and pumped into suitable-capacity anaerobic digesters where stabilization of organic waste takes place.

In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.

Biogas contain significant amount of hydrogen sulfide (H₂S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H₂S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H₂S into elemental sulfur. Biogas can be used as domestic cooking, industrial heating, combined heat and power (CHP) generation as well as a vehicle fuel. The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer.