Organometallic Chemistry

Direct Enantioselective Arylation of Amides

2012-02-07T14:26:00.001+05:30

Angewchem

Synthesis of 3-Fluoro-3-aryl Oxindoles: Direct Enantioselective Arylation of Amides
Linglin Wu, Laura Falivene, Dr. Emma Drinkel, Sharday Grant, Priv.-Doz. Dr. Anthony Linden, Prof. Dr. Luigi Cavallo and Prof. Dr. Reto Dorta

Cooperative Effects in Palladium-Catalyzed Enantioselective C(sp3)–H Functionalization

2012-02-07T14:24:00.002+05:30

Angewchem

Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium-Catalyzed Enantioselective C(sp³)–H Functionalization
Tanguy Saget, Sébastien J. Lemouzy and Prof. Dr. Nicolai Cramer

spirocyclic oxindoles via a direct C–H, Ar–H functionalisation

2012-02-07T14:18:00.001+05:30

Copper-catalysed approach to spirocyclic oxindoles via a direct C–H, Ar–H functionalisation
Catherine L. Moody, Vilius Franckevičius, Pauline Drouhin, Johannes E.M.N. Klein, Richard J.K. Taylor

Oxidation of the Methylene Group of Aryl(di)azinylmethanes

2012-02-01T00:05:00.003+05:30

Angewchem

Synthesis of Aryl(di)azinyl Ketones through Copper- and Iron-catalyzed Oxidation of the Methylene Group of Aryl(di)azinylmethanes
Johan De Houwer, Prof. Dr. Kourosch Abbaspour Tehrani and Prof. Dr. Bert U. W. Maes

Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones

2012-02-01T00:04:00.001+05:30

Angewchem

Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon–Carbon Bond Cleavage
Dr. Lantao Liu, Dr. Naoki Ishida and Prof. Dr. Masahiro Murakami

A General Solution for the 2-Pyridyl Problem

2012-02-01T00:02:00.004+05:30

Angewchem

A General Solution for the 2-Pyridyl Problem
Graham R. Dick, Eric M. Woerly and Prof. Martin D. Burke

Oxidative Trifluoromethylthiolation of Aryl Boronic Acids

2012-02-01T00:01:00.000+05:30

Angewchem

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF₃ and Elemental Sulfur
Chao Chen, Yan Xie, Lingling Chu, Dr. Ruo-Wen Wang, Prof. Dr. Xingang Zhang and Prof. Dr. Feng-Ling Qing

Catalytic Enantioselective Saucy–Marbet Claisen Rearrangement

2012-01-31T23:59:00.003+05:30

Angewchem

Asymmetric Synthesis of Allenyl Oxindoles and Spirooxindoles by a Catalytic Enantioselective Saucy–Marbet Claisen Rearrangement
Trung Cao, Joshua Deitch, Dr. Elizabeth C. Linton and Prof. Marisa C. Kozlowski

Dehydrogenative Aryl-Aryl Bond Formation

2012-01-31T23:58:00.000+05:30

Angewchem

[Rh^IIICp*]-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation
Dr. Joanna Wencel-Delord, Corinna Nimphius, Prof. Dr. Frederic W. Patureau and Prof. Dr. Frank Glorius

Stereoselective Metal-Free Oxyaminations

2012-01-31T23:54:00.002+05:30

Angewchem

Highly Stereoselective Metal-Free Oxyaminations Using Chiral Hypervalent Iodine Reagents
Umar Farid and Prof. Dr. Thomas Wirth

Intramolecular Redox-Triggered C-H Functionalization

2012-01-31T23:51:00.002+05:30

Angewchem

Intramolecular Redox-Triggered C-H Functionalization
Dr. Igor D. Jurberg, Dr. Bo Peng, Eckhard Wöstefeld, Maximilian Wasserloos and Dr. Nuno Maulide

Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes

2012-01-31T23:50:00.000+05:30

Angewchem

Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic Cleavage of the C(sp³)-Si Bond
Dr. Yun Liang, Weizhi Geng, Junnian Wei and Prof. Dr. Zhenfeng Xi

Carbomagnesiation of Alkynyl(aryl)thioethers

2012-01-31T23:48:00.000+05:30

Angewchem

Synthesis of Functionalized Benzo[b]thiophenes by the Intramolecular Copper-Catalyzed Carbomagnesiation of Alkynyl(aryl)thioethers
M. Sc. Thomas Kunz and Prof. Dr. Paul Knochel

General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

2012-01-31T23:46:00.001+05:30

Angewchem

Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides
Dr. Shoubhik Das, Bianca Wendt, Dr. Konstanze Möller, Dr. Kathrin Junge and Prof. Dr. Matthias Beller

Easy Access to Functionalized Pyrroles

2012-01-31T23:43:00.000+05:30

Angewchem

Highly Regioselective Migration of the Sulfonyl Group: Easy Access to Functionalized Pyrroles
Xiaoyi Xin, Dr. Dongping Wang, Dr. Xincheng Li and Prof. Dr. Boshun Wan

Intramolecular Oxidative Oxyarylation of Hydroxyalkenes

2012-01-31T23:41:00.002+05:30

Angewchem

Combined Oxypalladation/C-H Functionalization: Palladium(II)-Catalyzed Intramolecular Oxidative Oxyarylation of Hydroxyalkenes
Rong Zhu and Prof. Dr. Stephen L. Buchwald

Highly Efficient Narasaka–Heck Cyclizations

2012-01-31T23:40:00.000+05:30

Angewchem

Highly Efficient Narasaka–Heck Cyclizations Mediated by P(3,5-(CF₃)₂C₆H₃)₃: Facile Access to N-Heterobicyclic Scaffolds
Adele Faulkner and Dr. John F. Bower

Enantioselective Synthesis of Spiro Cyclopentane-1,3′-indoles

2012-01-31T23:38:00.001+05:30

Angewchem

Enantioselective Synthesis of Spiro Cyclopentane-1,3′-indoles and 2,3,4,9-Tetrahydro-1H-carbazoles by Iridium-Catalyzed Allylic Dearomatization and Stereospecific Migration
Qing-Feng Wu, Chao Zheng and Prof. Dr. Shu-Li You

Conversion of Ketones to Enamides with Ammonia and Acetic Anhydride

2012-01-31T23:35:00.001+05:30

Angewchem

Direct Titanium-Mediated Conversion of Ketones to Enamides with Ammonia and Acetic Anhydride
Dr. Jonathan T. Reeves, Zhulin Tan, Dr. Zhengxu S. Han, Dr. Guisheng Li, Dr. Yongda Zhang, Yibo Xu, Dr. Diana C. Reeves, Dr. Nina C. Gonnella, Dr. Shengli Ma, Dr. Heewon Lee, Dr. Bruce Z. Lu and Dr. Chris H. Senanayake

Asymmetric Hydrogenation of Benzofurans

2012-01-31T23:33:00.001+05:30

Angewchem

Ruthenium NHC Catalyzed Highly Asymmetric Hydrogenation of Benzofurans
Dr. Nuria Ortega, Slawomir Urban, Bernhard Beiring and Prof. Dr. Frank Glorius

Oxidative C–H/N–H Bond Functionalizations of Anilines

2012-01-31T23:27:00.003+05:30

Cationic Ruthenium(II) Catalysts for Oxidative C–H/N–H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water
Lutz Ackermann and Alexander V. Lygin

Pd-Catalyzed Regioselective C–H Olefination/Cyclization Sequence

2012-01-31T23:26:00.000+05:30

Synthesis of Indolo [1,2-a]Quinoxalines via a Pd-Catalyzed Regioselective C–H Olefination/Cyclization Sequence
Liang Wang, Wei Guo, Xiao-Xiao Zhang, Xu-Dong Xia, and Wen-Jing Xiao

Oxidative C–H Bond Olefination of N-Methoxybenzamides

2012-01-31T23:23:00.002+05:30

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group
Bin Li, Jianfeng Ma, Nuancheng Wang, Huiliang Feng, Shansheng Xu, and Baiquan Wang

Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

2012-01-31T23:21:00.001+05:30

Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages
Lutz Ackermann, Jola Pospech, Karolina Graczyk, and Karsten Rauch

One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

2012-01-31T23:19:00.002+05:30

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes
Alexey Kuznetsov and Vladimir Gevorgyan